Daniel Rabinovich
List of Publications
A. Columbia University (1989-1994)
(1) ÒHexakis(trimethylphosphine)tungsten(0): Synthesis, Structure, and ReactivityÓ
Rabinovich, D.; Parkin, G. J. Am. Chem. Soc. 1990, 112, 5381-5383.
(2) ÒCompetitive sp3 and sp2 C-H Bond
Activation of Phenols by W(PMe3)6 and W(PMe3)4(h2-CH2PMe2)H:
Formation of Four- and Five-Membered OxametallacyclesÓ Rabinovich, D.; Zelman, R.; Parkin, G. J.
Am. Chem. Soc. 1990, 112,
9632-9633.
(3) ÒThe Syntheses, Structures,
and Reactivity of Monomeric Tungsten(IV) and Tungsten(VI) Bis(sulfido) Complexes: Facile Elimination of H2 from H2SÓ Rabinovich, D.; Parkin, G. J. Am.
Chem. Soc. 1991, 113,
5904-5905.
(4) ÒSynthesis and Structure of
W(PMe3)4(Te)2: The
First Transition-Metal Complex with a Terminal Tellurido LigandÓ Rabinovich, D.; Parkin, G. J. Am.
Chem. Soc. 1991, 113,
9421-9422.
(5) ÒSynthetic, Structural, and
Mechanistic Studies of the C-H Bond Activation of Phenols by W(PMe3)6 and W(PMe3)4(h2‑CH2PMe2)HÓ Rabinovich, D.; Zelman, R.; Parkin, G. J.
Am. Chem. Soc. 1992, 114,
4611-4621.
(6) ÒA Mechanistic Study of the
Oxidative-Addition of H2 to W(PMe3)4I2:
Observation of an Inverse Equilibrium Isotope EffectÓ Rabinovich, D.; Parkin, G. J. Am.
Chem. Soc. 1993, 115,
353-354.
(7) ÒIsocyanide-Induced Coupling
of Terminal Tellurido Ligands: The
Synthesis and Structure of W(PMe3)(CNBut)4(h2-Te2)Ó
Rabinovich, D.; Parkin, G. J. Am. Chem. Soc. 1993, 115, 9822-9823.
(8) ÒSyntheses, Structures, and Reactivities
of Terminal Selenido Complexes of TungstenÓ Rabinovich, D.; Parkin, G. Inorg. Chem. 1994, 33, 2313-2314.
(9) ÒOxidative-Cleavage of the
Te-Te Bond in h2‑Ditellurido Complexes: Syntheses and Structures of M(PMe3)4(h2-Te2)H2 (M = Mo, W)Ó Murphy, V. J.; Rabinovich, D.; Parkin,
G. J. Chem. Soc., Chem. Commun. 1995, 1099-1100.
(10) ÒFalse Minima and the Perils of a Polar
Axis in X-ray Structure Solutions:
Molecular Structures of W(PMe3)4H2X2 (X = F, Cl, Br) and W(PMe3)4H2F2(H2O)Ó
Murphy, V. J.; Rabinovich, D.; Parkin, G. J. Am. Chem. Soc. 1995, 117, 9762-9763.
See also: C & E News 1995, 73 (40), 27-29.
(11) ÒTerminal Sulfido, Selenido, and
Tellurido Complexes of TungstenÓ
Rabinovich, D.; Parkin, G. Inorg. Chem. 1995, 34, 6341-6361.
(12) ÒFalse Minima in X-ray Structure
Solutions Associated with a ÔPartial Polar AmbiguityÕ: Single Crystal X-ray and Neutron
Diffraction Studies on the Eight-Coordinate Tungsten Hydride Complexes, W(PMe3)4H2X2 (X = F, Cl, Br, I) and
W(PMe3)4H2F(FHF)Ó
Murphy, V. J.; Rabinovich, D.; Hascall, T.; Klooster, W. T.; Koetzle, T.
F.; Parkin, G. J. Am. Chem. Soc. 1998, 120,
4372-4387.
(13) ÒMechanistic and Theoretical Analysis of
the Oxidative Addition of H2 to Six‑Coordinate
Molybdenum and Tungsten Complexes M(PMe3)4X2 (M = Mo, W; X = F, Cl,
Br, I): An Inverse Equilibrium
Isotope Effect and an Unprecedented Halide DependanceÓ Hascall, T.; Rabinovich, D.; Murphy, V.
J.; Beachy, M. D.; Friesner, R. A.; Parkin, G. J. Am. Chem. Soc. 1999, 121, 11402-11417.
B. Los Alamos National Laboratory
(1994-1996)
(14) ÒNew Dicarbollide Complexes of
UraniumÓ Rabinovich, D.; Haswell,
C. M.; Scott, B. L.; Miller, R. L.; Nielsen, J. B.; Abney, K. D. Inorg.
Chem. 1996, 35,
1425-1426.
(15) ÒTetrachlorobis(N,N,NÕ,NÕ-tetramethylenediamine-N,NÕ)thorium(IV)Ó
Rabinovich, D.; Schimek, G. L.; Pennington, W. T.; Nielsen, J. B.;
Abney, K. D. Acta Crystallogr. 1997, C53,
191-193.
(16) ÒSynthesis of [Li(THF)4]2[Th(h2-C2B9H11)2X2] (X = Cl, Br, I): the First Dicarbollide Complexes of ThoriumÓ Rabinovich, D.; Chamberlin, R. M.;
Scott, B. L.; Nielsen, J. B.; Abney, K. D. Inorg. Chem. 1997, 36, 4216-4217.
(17) ÒDibromobis(h5-pentamethylcyclopentadienyl)thorium(IV)Ó Rabinovich, D.; Schimek, G. L.;
Pennington, W. T.; Nielsen, J. B.; Abney, K. D. Acta Crystallogr. 1997, C53, 1794-1797.
(18) ÒTrimethylsilyl Iodide as a Halide
Exchange Reagent in Inorganic Chemistry:
Synthesis and Structure of Cp*2ThI2 (Cp* = h5-C5Me5)Ó Rabinovich, D.; Bott, S. G.; Nielsen,
J. B.; Abney, K. D. Inorg. Chim. Acta. 1998, 274, 232-235.
(19) ÒOctaaquabromouranium(IV) Tribromide
Monohydrate, [UBr(H2O)8]Br3.H2OÓ
Rabinovich, D.; Schimek, G. L.; Pennington, W. T.; Nielsen, J. B.;
Abney, K. D. Acta Crystallogr. 1998, C54,
1740-1742.
(20) ÒMolecular Structure of ThBr4(DME)2 (DME =
1,2-dimethoxyethane)Ó Rabinovich,
D.; Scott, B. L.; Nielsen, J. B.; Abney, K. D. J. Chem. Crystallogr. 1999, 29, 243-246.
C. UNC Charlotte (1996-)
(21) ÒMethyltris(pyrazolyl)silanes: New Tripodal Nitrogen-Donor
LigandsÓ Pullen, E. E.; Rheingold,
A. L.; Rabinovich, D. Inorg. Chem. Commun. 1999, 2, 194-196.
(22) ÒTris[(alkylthio)methyl]silanes: Syntheses and Structures of Chromium,
Molybdenum, and Tungsten Complexes with a Tripodal Thioether LigandÓ Yim, H. W.; Tran, L. M.; Dobbin, E. D.;
Rabinovich, D.; Liable-Sands, L. M.; Incarvito, C. D.; Lam, K.‑C.;
Rheingold, A. L. Inorg. Chem. 1999, 38,
2211-2215.
(23) ÒOne-Dimensional Copper(I) Coordination
Polymers Based on a Tridentate Thioether LigandÓ Yim, H. W.; Tran, L. M.; Pullen, E. E.; Rabinovich, D.;
Liable-Sands, L. M.; Concolino, T. E.; Rheingold, A. L. Inorg. Chem. 1999, 38, 6234-6239.
(24) ÒMetallurgy in the Laboratory: Preparation of Pure AntimonyÓ OÕKlatner, B. L.; Rabinovich, D. J.
Chem. Educ. 2000, 77,
251-252.
(25) ÒSyntheses and Structures of
Methyltris(pyrazolyl)silane Complexes of the Group 6 MetalsÓ Pullen, E. E.; Rabinovich, D.;
Incarvito, C. D.; Concolino, T. E.; Rheingold, A. L. Inorg. Chem. 2000, 39, 1561-1567.
(26) ÒBismuth(III) Thioether Chemistry: Synthesis and Structure of a
Coordination Polymer Derived from BiCl3 and
MeSi(CH2SMe)3Ó Yim, H. W.; Lam. K.‑C.;
Rheingold, A. L.; Rabinovich, D. Polyhedron 2000, 19, 849-853.
(27) ÒSynthesis and Structure of {h3-MeSi(CH2SPh)3}Cr(CO)3: How
Long Can a Cr(0)—S(thioether) Bond Length Be?Ó Blackwell III, W. C.; Bunich, D.; Concolino, T. E.;
Rheingold, A. L.; Rabinovich, D. Inorg. Chem. Commun. 2000, 3, 325-327.
(28) ÒZinc Bis(pyrazolyl)silane
ComplexesÓ Richburg, L. M.;
Farouq, J. A.; Incarvito, C. D.; Rheingold, A. L.; Rabinovich, D. Polyhedron 2000, 19, 1815-1820.
(29) ÒSynthesis and Characterization of Two
New Bulky Tris(mercaptoimidazolyl)borate Ligands and their Zinc and Cadmium
ComplexesÓ Bakbak, S.; Bhatia, V.
K.; Incarvito, C. D.; Rheingold, A. L.; Rabinovich, D. Polyhedron 2001, 20, 3343-3348.
(30) ÒModeling Nickel Hydrogenases: Synthesis and Structure of a Distorted
Octahedral Complex with an Unprecedented [NiS4H2] CoreÓ
Alvarez, H. M.; Krawiec, M.; Donovan‑Merkert, B. T.; Fouzi, M.;
Rabinovich, D. Inorg. Chem. 2001, 40,
5736-5737.
(31) ÒSynthesis and Characterization of Novel
Mononuclear Cadmium Thiolate Complexes in a Sulfur-Rich EnvironmentÓ Bakbak, S.; Incarvito, C. D.;
Rheingold, A. L.; Rabinovich, D. Inorg. Chem. 2002, 41, 998-1001.
(32) ÒNovel Spherical Assembly of Gold
Nanoparticles Mediated by a Tetradentate ThioetherÓ Maye, M. M.; Chun, S. C.; Rabinovich, D.; Zhong, C.‑J.
J. Am. Chem. Soc. 2002, 124,
4958-4959.
(33) ÒBulky
Tris(mercaptoimidazolyl)borates:
Synthesis and Molecular Structures of the Group 12 Metal Complexes (TmtBu)MBr (M = Zn, Cd, Hg)Ó White, J. L.; Tanski, J. M.; Rabinovich, D. J. Chem.
Soc., Dalton Trans. 2002, 2987-2991.
(34) Ò[Bis(2-mercapto-1-methylimidazol-3-yl)borato](triphenylphosphine)gold(I)Ó Mohamed, A. A.; Rabinovich, D.;
Fackler, J. P. Acta Crystallogr. 2002, E58,
m726-m727.
(35) ÒConstruction of Spherical Assembly of
Gold Nanoparticles Using Tetra[(methylthio)methyl]silane as LigandÓ Maye, M. M.; Lim, I.-I. S.; Luo, J.;
Han, L.; Rabinovich, D.; Chen, S.; Maye, M. P.; Zhong, C.‑J. Mat. Res.
Soc. Symp. Proc. 2003, 739,
H2.6.1-H2.6.6.
(36) ÒHomoleptic Group 12 Metal
Bis(mercaptoimidazolyl)borate Complexes M[BmR]2 (M = Zn, Cd, Hg)Ó Alvarez, H. M.; Tran, T. B.; Richter, M. A.; Alyounes, D.
M.; Rabinovich, D.; Tanski, J. M.; Krawiec, M. Inorg. Chem. 2003, 42, 2149-2156.
(37) ÒSynthesis and Structural
Characterization of 2-mercapto-1‑tert‑butylimidazole and its Group 12 Metal
Derivatives (HmimtBu)2MBr2 (M = Zn, Cd, Hg)Ó White, J. L.; Tanski, J. M.; Churchill, D. G.; Rheingold, A.
L.; Rabinovich, D. J. Chem. Crystallogr. 2003, 33, 437-445.
(38) Òcis-Dichlorotetrakis(2-mercapto-1-tert-butylimidazole)lead(II)Ó Evans, R. N.; Mihalcik, D. J.; Rabinovich, D.; Jones, D. S. Acta
Crystallogr. 2003, E59,
m370-m372.
(39) ÒSize-Controlled Assembly of Gold
Nanoparticles Induced by a Tridentate Thioether LigandÓ Maye, M. M.; Luo, J.; Lim, I.‑I.
S.; Han, L.; Kariuki, N. N.; Rabinovich, D.; Liu, T.; Zhong, C.‑J. J.
Am. Chem. Soc. 2003, 125,
9906-9907.
(40) ÒDi‑m‑iodo‑bis{[methyltris(methylthio)methyl]silane‑k2S,SÕ]copper(I)}Ó Yim, H. W.; Rabinovich, D.; Lam, K.‑C.;
Golen, J. A.; Rheingold, A. L. Acta Crystallogr. 2003, E59, m556-m558.
(41) ÒBis(mercaptoimidazolyl)borates and the
Control of Nuclearity in Cadmium Thiolate ComplexesÓ Philson, L. A.; Alyounes, D. M.; Zakharov, L. N.; Rheingold,
A. L.; Rabinovich, D. Polyhedron 2003, 22,
3461-3466.
(42) ÒPoly(mercaptoimidazolyl)borate chemistry
and the predominance of k3‑S,S,H
over k2‑S,S
or k3‑S,S,S
coordination modes: unexpected formation
of square pyramidal Ni(II) complexesÓ
Alvarez, H. M.; Tanski, J. M.; Rabinovich, D. Polyhedron 2004, 23, 395-403.
(43) ÒThallium
Bis(mercaptoimidazolyl)boratesÓ
Alvarez, H. M.; Gillespie, P. A.; Gause, C. D.; Rheingold, A. L.; Golen,
J. A.; Rabinovich, D. Polyhedron 2004, 23,
617-622.
(44) ÒCobalt Tris(mercaptoimidazolyl)borate
Complexes: Synthetic Studies and
the Structure of the First CobaltaboratraneÓ Mihalcik, D. J.; White, J. L.; Tanski, J. M.; Zakharov, L.
N.; Yap, G. P. A.; Incarvito, C. D.; Rheingold, A. L.; Rabinovich, D. Dalton
Trans. 2004, 1626-1634.
(45) ÒManganese(I)
Poly(mercaptoimidazolyl)borate Complexes:
Spectroscopic and Structural Characterization of MnÉH—B Interactions in Solution and in
the Solid StateÓ Graham, L. A.;
Fout, A. R.; Kuehne, K. R.; White, J. L.; Marks, F. M.; Yap, G. P. A.;
Zakharov, L. N.; Rheingold, A. L.; Rabinovich, D. Dalton Trans. 2005,
171-180.
(46) ÒMediator–Template Assembly of
NanoparticlesÓ Maye, M. M.; Lim,
I.‑I. S.; Luo, J.; Rab, Z.; Rabinovich, D.; Liu, T.; Zhong, C.‑J. J.
Am. Chem. Soc. 2005, 127,
1519-1529.
(47) ÒFormation of Extended 1D Coordination
Polymers in Tetrathioether Complexes of Mercury(II): Effect of the Organic Substituents on the Crystal Structures
of {Si(CH2SR)4}HgBr2 (R = Me, Ph)Ó
Peindy, H. N.; Guyon, F.; Knorr, M.; Smith, A. B.; Farouq, J. A.; Islas,
S. A.; Rabinovich, D.; Golen, J. A.; Strohmann, C. Inorg. Chem. Commun. 2005, 8, 479-482.
(48) ÒTris(mercaptoimidazolyl)borate Complexes
of the Coinage Metals: Syntheses
and Molecular Structures of the First Gold Compounds and Related Copper and
Silver DerivativesÓ Patel, D. V.;
Mihalcik, D. J.; Kreisel, K. A.; Yap, Glenn P. A.; Zakharov, L. N.; Kassel, W.
S.; Rheingold, A. L.; Rabinovich, D. Dalton Trans. 2005,
2410-2416.
(49) ÒPoly(mercaptoimidazolyl)borate Complexes
of Cadmium and MercuryÓ
Rabinovich, D. Struct. Bond. 2006, 120,
143-162.
(50) Ò[Bis(3‑methyl‑2-thioxo‑2,3‑dihydro‑1H‑imidazolyl)borato‑k2S,SÕ]dibromoindium(III)Ó Hill, S. C.; Jones, D. S.; Rabinovich,
D. Acta Crystallogr. 2006, E62,
m702-m704.
(51) ÒGrowth and Optical Properties of
Wurtzite-Type CdS NanocrystalsÓ
Cao, H.; Wang, G.; Zhang, S.; Zhang, X.; Rabinovich, D. Inorg. Chem. 2006, 45, 5103-5108.
(52) ÒGold(I) Tris(mercaptoimidazolyl)borate
Chemistry: Synthesis and Molecular
Structure of the First Trinuclear TmR Complex
of a Transition MetalÓ Patel, D.
V.; Kreisel, K. A.; Yap, G. P. A.; Rabinovich, D. Inorg. Chem. Commun. 2006, 9, 748-750.
(53) ÒGeneration and Optical Properties of
Monodisperse Wurtzite-Type ZnS MicrospheresÓ Wu, Q.; Cao, H.; Zhang, S.; Zhang, X.; Rabinovich, D. Inorg.
Chem. 2006, 45,
7316-7322.
(54) ÒGeneral Classification of Organometallic
ReactionsÓ Rabinovich, D. In Comprehensive
Organometallic Chemistry III;
Crabtree, R. H., Mingos, D. M. P., Eds.; Elsevier: Oxford, 2007; Vol. 1, Chapter 1.03, pp 93-118.
(55) ÒNickel Nitrosyl Complexes in a
Sulfur-Rich Environment: the First
Poly(mercapto-imidazolyl)borate DerivativesÓ Maffett, L. S.; Gunter, K. L.; Kreisel, K. A.; Yap, G. P.
A.; Rabinovich, D. Polyhedron 2007, 26,
4758-4764.
(56) ÒLead(II) in a Sulfur-Rich
Environment: Synthesis and
Molecular Structure of the First Dinuclear Bis(mercaptoimidazolyl)methane
ComplexÓ Pinder, T. A.;
VanDerveer, D.; Rabinovich, D. Inorg. Chem. Commun. 2007, 10, 1381-1384.
(57) ÒFemtosecond Isomerization in a
Photochromic Molecular SwitchÓ
Mockus, N. V.; Rabinovich, D.; Petersen, J. L.; Rack, J. J. Angew.
Chem. Int. Ed., in press.
Last
updated: 19 December 2007